synthesis/tests/chemistry.test.ts

import { describe, it, expect } from 'vitest';
import { ElementRegistry } from '../src/chemistry/elements';
import { CompoundRegistry } from '../src/chemistry/compounds';
import { ReactionEngine } from '../src/chemistry/engine';

// =============================================================================
// ELEMENT REGISTRY
// =============================================================================

describe('ElementRegistry', () => {
  it('should load all 20 elements', () => {
    expect(ElementRegistry.count()).toBe(20);
  });

  it('should look up elements by symbol', () => {
    const na = ElementRegistry.getBySymbol('Na');
    expect(na).toBeDefined();
    expect(na!.name).toBe('Sodium');
    expect(na!.nameRu).toBe('Натрий');
    expect(na!.atomicNumber).toBe(11);
    expect(na!.atomicMass).toBeCloseTo(22.990, 2);
    expect(na!.category).toBe('alkali-metal');
  });

  it('should look up elements by atomic number', () => {
    const fe = ElementRegistry.getByNumber(26);
    expect(fe).toBeDefined();
    expect(fe!.symbol).toBe('Fe');
    expect(fe!.name).toBe('Iron');
  });

  it('should return undefined for non-existent elements', () => {
    expect(ElementRegistry.getBySymbol('Xx')).toBeUndefined();
    expect(ElementRegistry.getByNumber(999)).toBeUndefined();
  });

  it('should have correct data for all elements (real periodic table)', () => {
    const h = ElementRegistry.getBySymbol('H')!;
    expect(h.atomicNumber).toBe(1);
    expect(h.atomicMass).toBeCloseTo(1.008, 2);
    expect(h.state).toBe('gas');

    const hg = ElementRegistry.getBySymbol('Hg')!;
    expect(hg.atomicNumber).toBe(80);
    expect(hg.state).toBe('liquid'); // Only metal liquid at room temp!

    const he = ElementRegistry.getBySymbol('He')!;
    expect(he.category).toBe('noble-gas');
    expect(he.electronegativity).toBe(0);

    const au = ElementRegistry.getBySymbol('Au')!;
    expect(au.atomicNumber).toBe(79);
    expect(au.category).toBe('transition-metal');
  });

  it('should identify elements correctly', () => {
    expect(ElementRegistry.isElement('Na')).toBe(true);
    expect(ElementRegistry.isElement('Fe')).toBe(true);
    expect(ElementRegistry.isElement('NaCl')).toBe(false);
    expect(ElementRegistry.isElement('H2O')).toBe(false);
  });
});

// =============================================================================
// COMPOUND REGISTRY
// =============================================================================

describe('CompoundRegistry', () => {
  it('should load all compounds', () => {
    expect(CompoundRegistry.count()).toBeGreaterThanOrEqual(20);
  });

  it('should look up compounds by id', () => {
    const water = CompoundRegistry.getById('H2O');
    expect(water).toBeDefined();
    expect(water!.name).toBe('Water');
    expect(water!.formula).toBe('H₂O');
    expect(water!.mass).toBeCloseTo(18.015, 2);
    expect(water!.state).toBe('liquid');
  });

  it('should have game effects for each compound', () => {
    const salt = CompoundRegistry.getById('NaCl')!;
    expect(salt.gameEffects).toContain('preservation');

    const gunpowder = CompoundRegistry.getById('GUNPOWDER')!;
    expect(gunpowder.gameEffects).toContain('explosive');
    expect(gunpowder.properties.explosive).toBe(true);
  });

  it('should correctly flag dangerous compounds', () => {
    const hcl = CompoundRegistry.getById('HCl')!;
    expect(hcl.properties.acidic).toBe(true);
    expect(hcl.properties.corrosive).toBe(true);

    const co = CompoundRegistry.getById('CO')!;
    expect(co.properties.toxic).toBe(true);

    const naoh = CompoundRegistry.getById('NaOH')!;
    expect(naoh.properties.basic).toBe(true);
    expect(naoh.properties.corrosive).toBe(true);
  });

  it('should identify compounds correctly', () => {
    expect(CompoundRegistry.isCompound('NaCl')).toBe(true);
    expect(CompoundRegistry.isCompound('H2O')).toBe(true);
    expect(CompoundRegistry.isCompound('Na')).toBe(false);
  });
});

// =============================================================================
// REACTION ENGINE — SUCCESSFUL REACTIONS
// =============================================================================

describe('ReactionEngine — success', () => {
  it('should produce NaCl from Na + Cl', () => {
    const result = ReactionEngine.react([
      { id: 'Na', count: 1 },
      { id: 'Cl', count: 1 },
    ]);
    expect(result.success).toBe(true);
    expect(result.products).toEqual([{ id: 'NaCl', count: 1 }]);
  });

  it('should produce H2O from 2H + O', () => {
    const result = ReactionEngine.react(
      [
        { id: 'H', count: 2 },
        { id: 'O', count: 1 },
      ],
      { minTemp: 500 },
    );
    expect(result.success).toBe(true);
    expect(result.products).toEqual([{ id: 'H2O', count: 1 }]);
  });

  it('should produce CO2 from C + 2O with heat', () => {
    const result = ReactionEngine.react(
      [
        { id: 'C', count: 1 },
        { id: 'O', count: 2 },
      ],
      { minTemp: 500 },
    );
    expect(result.success).toBe(true);
    expect(result.products).toEqual([{ id: 'CO2', count: 1 }]);
    expect(result.reaction!.type).toBe('combustion');
  });

  it('should produce NaOH + H from Na + H2O (violent reaction)', () => {
    const result = ReactionEngine.react([
      { id: 'Na', count: 1 },
      { id: 'H2O', count: 1 },
    ]);
    expect(result.success).toBe(true);
    expect(result.products).toContainEqual({ id: 'NaOH', count: 1 });
    expect(result.products).toContainEqual({ id: 'H', count: 1 });
    expect(result.reaction!.energyChange).toBeLessThan(-50); // Very exothermic
  });

  it('should produce gunpowder from KNO3 + S + C', () => {
    const result = ReactionEngine.react([
      { id: 'KNO3', count: 1 },
      { id: 'S', count: 1 },
      { id: 'C', count: 1 },
    ]);
    expect(result.success).toBe(true);
    expect(result.products).toEqual([{ id: 'GUNPOWDER', count: 1 }]);
  });

  it('should produce thermite: Fe2O3 + 2Al → 2Fe + Al2O3', () => {
    const result = ReactionEngine.react(
      [
        { id: 'Fe2O3', count: 1 },
        { id: 'Al', count: 2 },
      ],
      { minTemp: 1000 },
    );
    expect(result.success).toBe(true);
    expect(result.products).toContainEqual({ id: 'Fe', count: 2 });
    expect(result.products).toContainEqual({ id: 'Al2O3', count: 1 });
    expect(result.reaction!.energyChange).toBe(-100); // Maximum exothermic
  });

  it('should produce NaCl + H2O from NaOH + HCl (neutralization)', () => {
    const result = ReactionEngine.react([
      { id: 'NaOH', count: 1 },
      { id: 'HCl', count: 1 },
    ]);
    expect(result.success).toBe(true);
    expect(result.products).toContainEqual({ id: 'NaCl', count: 1 });
    expect(result.products).toContainEqual({ id: 'H2O', count: 1 });
    expect(result.reaction!.type).toBe('acid-base');
  });

  it('should decompose H2O with energy input (electrolysis)', () => {
    const result = ReactionEngine.react(
      [{ id: 'H2O', count: 1 }],
      { requiresEnergy: true },
    );
    expect(result.success).toBe(true);
    expect(result.products).toContainEqual({ id: 'H', count: 2 });
    expect(result.products).toContainEqual({ id: 'O', count: 1 });
    expect(result.reaction!.energyChange).toBeGreaterThan(0); // Endothermic
  });

  it('reactant order should not matter (key is sorted)', () => {
    const r1 = ReactionEngine.react([
      { id: 'Cl', count: 1 },
      { id: 'Na', count: 1 },
    ]);
    const r2 = ReactionEngine.react([
      { id: 'Na', count: 1 },
      { id: 'Cl', count: 1 },
    ]);
    expect(r1.success).toBe(true);
    expect(r2.success).toBe(true);
    expect(r1.products).toEqual(r2.products);
  });
});

// =============================================================================
// REACTION ENGINE — FAILURES (educational)
// =============================================================================

describe('ReactionEngine — failures', () => {
  it('should reject noble gas reactions with explanation', () => {
    const result = ReactionEngine.react([
      { id: 'He', count: 1 },
      { id: 'O', count: 1 },
    ]);
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('noble gas');
    expect(result.failureReasonRu).toContain('благородный газ');
  });

  it('should reject gold reactions with explanation', () => {
    const result = ReactionEngine.react([
      { id: 'Au', count: 1 },
      { id: 'O', count: 1 },
    ]);
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('Gold');
  });

  it('should fail when heat is required but not provided', () => {
    const result = ReactionEngine.react([
      { id: 'C', count: 1 },
      { id: 'O', count: 2 },
    ]); // No heat
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('temperature');
  });

  it('should fail when catalyst is required but not provided', () => {
    const result = ReactionEngine.react(
      [
        { id: 'C', count: 1 },
        { id: 'H', count: 4 },
      ],
      { minTemp: 500 }, // Heat provided, but catalyst (Fe) missing
    );
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('catalyst');
  });

  it('should fail when energy is required but not provided', () => {
    const result = ReactionEngine.react([
      { id: 'H2O', count: 1 },
    ]); // Electrolysis needs energy
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('energy');
  });

  it('should fail for unknown substances', () => {
    const result = ReactionEngine.react([
      { id: 'Unobtainium', count: 1 },
      { id: 'Na', count: 1 },
    ]);
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('Unknown substance');
  });

  it('should fail for same element with itself', () => {
    const result = ReactionEngine.react([
      { id: 'Fe', count: 1 },
      { id: 'Fe', count: 1 },
    ]);
    expect(result.success).toBe(false);
    expect(result.failureReason).toBeDefined();
  });

  it('should suggest wrong proportions when elements match but counts differ', () => {
    // H + O exists? No, H:1+O:1 doesn't but H:2+O:1 does
    const result = ReactionEngine.react(
      [
        { id: 'H', count: 1 },
        { id: 'O', count: 1 },
      ],
      { minTemp: 500 },
    );
    expect(result.success).toBe(false);
    expect(result.failureReason).toContain('proportions');
  });
});

// =============================================================================
// REACTION ENGINE — METADATA
// =============================================================================

describe('ReactionEngine — metadata', () => {
  it('should have 30+ registered reactions', () => {
    expect(ReactionEngine.count()).toBeGreaterThanOrEqual(30);
  });

  it('should look up reactions by id', () => {
    const thermite = ReactionEngine.getById('redox_thermite');
    expect(thermite).toBeDefined();
    expect(thermite!.type).toBe('redox');
  });

  it('every reaction should have both English and Russian descriptions', () => {
    for (const r of ReactionEngine.getAll()) {
      expect(r.description.length).toBeGreaterThan(10);
      expect(r.descriptionRu.length).toBeGreaterThan(10);
    }
  });

  it('every reaction should have valid reactants and products', () => {
    for (const r of ReactionEngine.getAll()) {
      expect(r.reactants.length).toBeGreaterThanOrEqual(1);
      expect(r.products.length).toBeGreaterThanOrEqual(1);
      for (const reactant of r.reactants) {
        expect(reactant.count).toBeGreaterThan(0);
        const exists =
          ElementRegistry.isElement(reactant.id) || CompoundRegistry.isCompound(reactant.id);
        expect(exists, `Reactant "${reactant.id}" in reaction "${r.id}" not found`).toBe(true);
      }
      for (const product of r.products) {
        expect(product.count).toBeGreaterThan(0);
        const exists =
          ElementRegistry.isElement(product.id) || CompoundRegistry.isCompound(product.id);
        expect(exists, `Product "${product.id}" in reaction "${r.id}" not found`).toBe(true);
      }
    }
  });
});